A lot of people jump straight into romantic tension with Kirishima, but his whole deal is about reliability and that unfiltered heart-on-his-sleeve thing. Build scenes around that. Have your OC need backup, not necessarily in a fight but maybe facing some boring administrative nightmare at school, and he's just there, solid as a rock, offering to help carry stuff or talk to the teacher. The chemistry comes from how his steadfast nature meets her specific vulnerability. Maybe she's used to people flaking, and his simple, unwavering presence throws her. Show his admiration when she displays her own kind of bravery—not flashy like his, but quiet and persistent. The unshakable faith he has in others is his love language; let your OC earn it, then be startled by its weight.
Avoid making the OC a manic pixie dream girl who 'fixes' him. He's already pretty emotionally healthy! Conflict can come from them having different approaches to the same value. They both value bravery, but hers is calculated, his is instinctive. That causes friction before it becomes understanding. Let them cook together or work on a project; his direct compliments and her awkward, grateful reactions feel more real than any grand confession. The believable part is in the mundane moments where his bright, honest personality just naturally slots into the gaps in her life.