The only Spider-Man movie where Venom takes center stage as the main antagonist is 'Spider-Man 3' (2007), directed by Sam Raimi. It was a divisive entry—some fans loved the chaotic energy of Topher Grace's Eddie Brock transforming into the symbiote-fueled menace, while others felt it crammed too many villains (Sandman, New Goblin, and Venom) into one story. I personally enjoyed the black suit arc's psychological toll on Peter, even if Venom’s screen time felt rushed.
Funny enough, Sony later tried to course-correct with 'Venom' (2018) as a standalone antihero flick, but for pure Spidey vs. Venom showdowns, 'Spider-Man 3' remains the go-to. Though I wish we’d gotten more of that iconic rivalry, like the comics’ 'Maximum Carnage' intensity—maybe someday in the MCU!