If we're talking Romanogers, you can't get around Archive of Our Own. The tagging system is built for this kind of search. Filter for Steve Rogers/Natasha Romanoff, sort by kudos or hits, and you're in a bottomless pit of content. The top works there have thousands of kudos and are genuinely well-written—some authors treat them like an extended character study post-'Endgame', which is where a lot of the angst comes from.
Tumblr still holds a special place, though it's more for moodboards, snippets, and finding authors who link to their AO3. The community vibe is different; it's less about the stats and more about sharing a specific aesthetic or headcanon in real-time.
FF.net has a surprising amount, but the quality can be super hit-or-miss, and the interface feels ancient. I'd only check there if I've exhausted everything else. Honestly, my reading weeknights are mostly just alternating between AO3 and my Tumblr dash for new recs.