It's actually wild how many powers Rimuru ends up stacking by the time he's officially a Demon Lord. The obvious one is 'Predator' and its evolution, 'Gluttony', which lets him absorb basically anything – skills, magic, even other beings – and analyze or replicate them. That's the core cheat. But the post-harvest festival stuff is where it gets nuts. He gets 'Beelzebub', a supreme skill that's like an upgraded void version of Gluttony; it can store things in an imaginary space, absorb attacks, and even resurrect him.
Then there's the whole 'Great Sage' and later 'Raphael' intelligence guiding him, which is arguably his most broken ability because it optimizes everything automatically. He can analyze and integrate thousands of skills at once. He also gets 'Uriel', a defensive absolute skill that creates multibarrier shields and can isolate space. Combining these lets him do things like 'Covenant King Uriel' to protect his entire nation. Honestly, the list is so long it's almost comical – he's a walking repository of every major power in that world.
What I find more interesting than the raw power is how he uses it, though. A lot of his abilities are geared toward administration, protection, and creation, which fits his role as a leader rather than just a conqueror. The way 'Food Chain' links him to his subordinates and shares power upward is a unique twist on the typical overlord dynamic.