Ooh, this is my favorite kind of mashup. It’s tricky to balance the cold precision of a killer with genuine romantic heat, but when it works, it’s addicting. I gravitate towards series where the romance is a slow-burn consequence of the plot, not the sole driver. The 'Night Angel' trilogy by Brent Weeks is a cornerstone for a reason—Azoth’s journey from guild rat to wetboy is brutal, and his relationship with Elene is this fragile, grounding thing amidst all the violence. It feels earned.
For something more recent and purely in the romance lane, the 'Kings of the Underworld' series by Sam Crescent gets recommended a lot in certain circles. It’s very much ‘mafia assassin falls for target/innocent,’ which is a whole vibe if you’re in that mood. The stakes feel personal rather than world-ending, which shifts the tension. A lot of these live in the indie paranormal or dark romance space, so you have to sift a bit for writing style, but the trope is reliably present.
My personal dark horse suggestion is 'The Emperor’s Edge' by Lindsay Burook. It’s steampunk-fantasy with a disgraced enforcer recruiting a legendary assassin to save the emperor. The core relationship between Amaranthe and Sicarius is a masterpiece of glacial progression—he’s literally emotionally stunted from his training, and she’s all chaotic optimism. Watching trust build from professional necessity into something else is the entire payoff.