Shipping in 'Ben 10' fanfiction can get wild, which honestly is half the point. Most of the romantic focus lands on Ben and Gwen, though I’ve never warmed up to that specific dynamic—too much bickering turns me off, even if the 'enemies to lovers' arc is popular. The real depth, weirdly, comes from fics around Ben and Julie Yamamoto or Ben and Ester. Those relationships had canonical groundwork, so writers don't have to bend over backwards to make them believable. I'm always more drawn to stories that extrapolate from what the show gave us, rather than inventing entirely new chemistry from scratch.
Then you've got the side character pairings that have their own dedicated followings. Kevin and Gwen is huge, obviously, and I think the appeal is that edgy, reformed bad boy with the straight-laced magic-user dynamic. It offers a different flavor than Ben's hero journey. Some of the most interesting stuff I've stumbled on lately are rarepairs, like Rook Blonko and Kai Green, exploring what happens after the series ends with more mature characters. Those fics tend to be slower, more character-driven, and less about alien fights.
Crossover ships are another beast entirely. Ben paired with characters from 'Danny Phantom' or 'Generator Rex' pops up a lot in multi-fandom archives. The fun there isn't just romance; it's the clash of worlds and power systems. But honestly, the absolute best ship-focused fics I've read are the ones that treat the pairing as a vehicle to explore something else—like Gwen grappling with her Anodite heritage through a relationship, or Kevin's struggle with his past affecting his trust in a partner. The romance is there, but it's layered over solid character study, which keeps me reading.